简介
欧美高清砖一二区烷类化合物主要应用在有机合成及欧美高清砖一二区材料领域。在有机合成中,硅烷作为羟基 保护基大量存在,如三甲基氯硅烷,TBSCI,有时作为一个合成子载体存在,如乙烯基三甲基 硅烷,烯丙基三甲基硅烷,六甲基二硅硫烷等,从而实现相应的官能团化反应。欧美高清砖一二区材料领域有欧美高清砖一二区、硅油(硅脂、硅乳液、硅欧美高清砖一二区)、高温硫化硅橡胶、液体硅橡胶、硅 树脂、封端剂,含硅复合共聚物等。
应用介绍及参考文献
1
.如乙烯基三甲基硅烷作为一个“乙烯”合成子,用于
3+2
环加成反应,应用于有机合成过程中。
图片来源于期刊:
Vinyltrimethylsilane, Glenn J. Fegley Gerald L. Larson, Encyclopedia of Reagents for Organic Synthesis, 2008.
2.如烯丙基三甲基硅烷,作为一个烯丙基化试剂,应用于艾日布林或者前列素类似物的合成中。
图片来源于期刊:
W020050118565, WO2019102490
图片来源于期刊:
Gary A. Sulikowski et al Org. Lett. 2019, 21, 10048-10051
3.作为聚合引发剂,或者烯姪共聚物,参与烯姪聚合,形成功能性欧美高清砖一二区材料,如耐水性欧美高清砖一二区 粘合剂,修饰聚氟乙烯等
技术优势
产品纯度高,具有百公斤生产能力
Chemical Name |
Phenylsilane |
MDL Number |
MFCD00013478 |
EC Number |
211-772-5 |
CAS Number |
694-53-1 |
Synonym |
苯基硅烷 phenyl-silane Monophenylsilane Phenylsilane Silane, phenyl- Phenylsilane, silyl- phenylsilane Silylbenzene 苯硅烷 Phenylsilane,97% Fenylsilan Benzene, silyl- PHENYLSILANE CHLORODIMETHYL phenyl-silan |
Beilstein Registry Number |
2935169 |
PubChem Substance ID |
6327628 |
Reaxys-RN |
2935169 |
Chemical Name Translation |
苯硅烷 |
InChIKey |
PARWUHTVGZSQPD-UHFFFAOYSA-N |
LabNetwork Molecule ID |
LN00007171 |
InChI |
InChI=1S/C6H5Si/c7-6-4-2-1-3-5-6/h1-5H |
GHS Symbol
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 14500 mg/m3/2H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1227,1986
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 700 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1227,1986
Safety Statements |
|
-
S16
Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
-
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
-
S36/37
Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
-
S36/37/39
Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
-
S43
In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
-
S7/8
Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
|
UN Number |
3399 |
Risk Statements |
|
-
R11
Highly flammable 非常易燃
-
R14/15
Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
-
R20/22
Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
-
R36/37/38
Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
Storage condition |
Moisture Sensitive Flammables area |
Signal word |
Danger |
WGK Germany |
3 |
Precautionary statements |
|
-
P210
Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
-
P231+P232
-
P233
Keep container tightly closed. ?保持容器密闭。
-
P240
Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
-
P241
Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
-
P242
Use only non-sparking tools. 只能使用无火花工具。
-
P243
Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
-
P261
Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
-
P264
Wash hands thoroughly after handling. 处理后要彻底洗净双手。
-
P264+P265
-
P270
Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
-
P271
Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
-
P280
Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
-
P301+P312
-
P301+P312+P330
-
P301+P317
-
P302+P352
-
P302+P352+P332+P313+P362+P364
-
P303+
-
P303+P361+P353
-
P304+P312
-
P304+P340
-
P305+P351+P338
-
P305+P351+P338+P337+P313
-
P312
Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
-
P317
-
P319
-
P321
Specific treatment (see … on this label). 具体治疗(见本标签上的)。
-
P330
Rinse mouth. 漱口
-
P332+P313
-
P332+P317
-
P337+P313
-
P337+P317
-
P362
Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
-
P362+P364
-
P370+P378
-
P402+P404
-
P403+P233
-
P403+P235
-
P405
Store locked up. 上锁保管。
-
P422
Store contents under… 存储目录在…之下。
-
P501
Dispose of contents/container to..… 处理内容物/容器.....
|
Hazard statements |
|
-
H225
Highly flammable liquid and vapour 高度易燃液体和蒸气
-
H261
In contact with water releases flammable gas 与水接触时释放可燃气体。
-
H302
Harmful if swallowed 吞食有害
-
H315
Causes skin irritation 会刺激皮肤
-
H319
Causes serious eye irritation 严重刺激眼睛
-
H332
Harmful if inhaled 吸入有害
-
H335
May cause respiratory irritation 可能导致呼吸道刺激
|
Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
RTECS |
VV4825000 |
Packing Group |
II |
Hazard Codes |
4.3 F,Xn Xn;F |
Hazard Class |
3 |
{uni_hamburg} Short: II/14a
Title: Molecular Constants: Diamagnetic Molecules
Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E.
Editor: Hellwege, K.-H.; Hellwege, A.M.
Source: Landolt-Börnstein, New Series
Volume: II/14a
Page: 1-788
Year: 1982
Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy
ISBN: 3-540-11365-7
ISBN: 978-3-540-11365-2
Internet Resource: DOI:10.1007/b19966
RefComment: 196 figs., XI
{uni_hamburg} Short: II/2
Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds
Author: König, E.
Editor: Hellwege, K.-H.; Hellwege, A.M.
Source: Landolt-Börnstein, New Series
Volume: II/2
Year: 1966
ISBN: 3-540-03593-1
ISBN: 978-3-540-03593-0
Internet Resource: DOI:10.1007/b19948
RefComment: 170 figs., XII, 578 pages. Hardcover
Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
{uni_hamburg} Short: II/25D
Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms
Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
Editor: Kuchitsu, K.
Source: Landolt-Börnstein, New Series
Volume: II/25D
Year: 2003
Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
ISBN: 3-540-42860-7
ISBN: 978-3-540-42860-2
Internet Resource: DOI:10.1007/b75952
RefComment: VIII, 569 pages. Hardcover
RefComment: Written for scientists and researchers in the fields of chemistry and physics
Abstract: This fourth subvolume presents data on the geometric parameters (intern