Chemical Name |
Phenylmagnesium Chloride |
EC Number |
250-023-7 |
Beilstein Registry Number |
3587900 |
PubChem Substance ID |
7513 |
Synonym |
Chlorphenylmagnesium Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN chlorophenylmagnesium PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER Phenylmagnesiumchloride,2-3MinTHF PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran 氯化苯基鎂 PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN 氯化苯鎂 PHENYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L) 氯化苯基镁 chlorophenyl-magnesiu PHENYLMAGNESIUM CHLORIDE SOLUTION & Magnesium, chlorophenyl- PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN Phenylmagnesium chloride25 wt% solution in tetrahydrofuranAcroSeal§3 苯基氯化镁 Phenylchloromagnesium 苯基氯化镁 溶液 PHENYLMAGNESIUM CHLORIDE |
Merck Number |
7298 |
Chemical Name Translation |
苯基氯化镁 |
Reaxys-RN |
4576984 |
InChI |
InChI=1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q-1;;+2/p-1 |
MDL Number |
MFCD00000464 |
CAS Number |
100-59-4 |
GHS Symbol
Signal word |
|
WGK Germany |
3 |
Safety Statements |
|
-
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
-
S36/37/39
Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
-
S45
In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
-
S16
Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
-
S23
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
-
S33
Take precautionary measures against static discharges 对静电采取预防措施;
-
S30
Never add water to this product 切勿将水加入该产品中;
-
S62
If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
|
Risk Statements |
|
-
R11
Highly flammable 非常易燃
-
R19
May form explosive peroxides 可能生成易爆的过越做越想做怎么办搜狗百度百科质
-
R37
Irritating to respiratory system 刺激呼吸道
-
R14
Reacts violently with water 遇水会猛烈反应
-
R34
Causes burns 会导致灼伤
-
R36/37/38
Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
Precautionary statements |
|
-
P210
Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
-
P233
Keep container tightly closed. ?保持容器密闭。
-
P240
Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
-
P241
Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
-
P241+
-
P242
Use only non-sparking tools. 只能使用无火花工具。
-
P243
Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
-
P260
Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
-
P261
Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
-
P264
Wash hands thoroughly after handling. 处理后要彻底洗净双手。
-
P271
Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
-
P280
Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
-
P301+P330+P331
-
P303+P361+P353
-
P304+P340
-
P305+P351+P338
-
P305+P351+P338+P310
-
P310
Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
-
P321
Specific treatment (see … on this label). 具体治疗(见本标签上的)。
-
P363
Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
-
P370+P378
-
P403+P233
-
P403+P235
-
P405
Store locked up. 上锁保管。
-
P501
Dispose of contents/container to..… 处理内容物/容器.....
|
Hazard statements |
|
-
H225
Highly flammable liquid and vapour 高度易燃液体和蒸气
-
H314
Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
-
H335
May cause respiratory irritation 可能导致呼吸道刺激
-
H351
Suspected of causing cancer 怀疑致癌
|
Personal Protective Equipment |
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Packing Group |
II |
UN Number |
|
Storage condition |
充氩保存; 在25°C 以下可能引起镁盐结晶,移到温度稍高地方轻微摇动可分解固体。 water-free area Air & Moisture Sensitive 在25°C 以下可能引起镁盐结晶,移到温度稍高地方轻微摇动可分解固体。 |
Hazard Codes |
F,C |
Hazard Class |
3/8 |
Restrict |
危险品 |
{ALD} Merck:7298
{ALD} Merck:7298
Beilstein:16,929