Chemical Name |
Methylmagnesium bromide |
EC Number |
200-844-1 |
Beilstein Registry Number |
3535220 |
Reaxys-RN |
3909313 |
PubChem Substance ID |
87572429 |
Synonym |
Methyl magnesium bromide(in ethyl ether) methylmagnesium bromide sol. Methylmagnesium bromide, 1.4M solution in toluene/THF Methylmagnesium Bromide 2.0 M In n-Butyl Ether METHYLMAGNESIUM BROMIDE SOLUTION 甲基溴化镁 methyl-magnesiubromide(ethylethersolution)[qr] 甲基溴化镁, 3M乙醚溶液 溴甲基镁 Methylmagnesium bromide, 3M solution in diethyl ether 格利雅溶液 Methylmagnesium Bromide 1.0 M In Butyl Diglyme 甲基镁化溴 甲基溴鎂 Methylmagnesium Bromide 2.0 M In Tetrahydrofuran/Toluene 甲基溴化镁 溶液 Methylmagnesium Bromide 3.0 M In Diethyl Ether bromomethyl-magnesiu BROMOME 甲基溴化镁, 3M IN ETHER, PACKAGED UNDER ARGON IN RESEALABL METHYLMAGNESIUM BROMIDE, 3 |
Chemical Name Translation |
甲基溴化镁 |
LabNetwork Molecule ID |
LN00220157 |
InChI |
InChI=1S/CH3.BrH.Mg/h1H3;1H;/q-1;;+2/p-1 |
MDL Number |
MFCD00000041 |
CAS Number |
75-16-1 |
GHS Symbol
Signal word |
Danger |
WGK Germany |
2 |
Safety Statements |
|
-
S16
Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
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S23
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
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S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
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S33
Take precautionary measures against static discharges 对静电采取预防措施;
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S36/37/39
Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
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S43
In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
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S45
In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
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S6
Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中;
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S7/8
Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
|
Risk Statements |
|
-
R11
Highly flammable 非常易燃
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R14/15
Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
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R19
May form explosive peroxides 可能生成易爆的过麻w痘w传w媒w在线入口-在线免费完整版~高清片质
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R34
Causes burns 会导致灼伤
|
Precautionary statements |
|
-
P210
Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
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P222
Do not allow contact with air. 不要与空气接触。
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P223
Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
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P231+P232
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P233
Keep container tightly closed. ?保持容器密闭。
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P240
Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
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P241+P242+P243
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P260
Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
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P261
Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
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P264
Wash hands thoroughly after handling. 处理后要彻底洗净双手。
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P270
Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
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P271
Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
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P273
Avoid release to the environment. 避免释放到环境中。
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P280
Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
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P301+P310
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P301+P330+P331+P310
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P302+P352+P332+P313+P362+P364
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P303+P361+P353+P310+P363
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P304+P340+P310
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P305+P351+P338
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P305+P351+P338+P310
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P305+P351+P338+P337+P313
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P308+P311
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P310
Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
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P312
Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
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P332+P313
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P335+P334
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P337+P313
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P362
Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
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P370+P378
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P402+P404
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P403+P233
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P403+P235
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P405
Store locked up. 上锁保管。
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P422
Store contents under… 存储目录在…之下。
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P501
Dispose of contents/container to..… 处理内容物/容器.....
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UN Number |
3399 |
Hazard statements |
|
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H224
Extremely flammable liquid and vapour 极端易燃液体和蒸气
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H225
Highly flammable liquid and vapour 高度易燃液体和蒸气
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H226
Flammable liquid and vapour 易燃液体和蒸气
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H260
In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
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H261
In contact with water releases flammable gas 与水接触时释放可燃气体。
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H302
Harmful if swallowed 吞食有害
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H304
May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
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H314
Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
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H335
May cause respiratory irritation 可能导致呼吸道刺激
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H336
May cause drowsiness or dizziness 肯能导致嗜睡或头晕
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H351
Suspected of causing cancer 怀疑致癌
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H361d
Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
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H373
May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
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H412
Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
|
Personal Protective Equipment |
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Packing Group |
II |
Storage condition |
water-free area Air & Moisture Sensitive 充氩保存 |
Hazard Codes |
4.3 F,C |
Hazard Class |
4.3/3 |
RTECS |
OM3700000 |
Warnings |
危化品目录(2015) |
Restrict |
危险品 |
⑴.常温差压下为固体。与水接触有剧烈反应。对水、光和空气敏感。
⑵. 吸入、摄入或经皮肤吸收后对身体有害。对眼睛、皮肤、 粘膜、和上呼吸道有强烈的刺激作用。接触后可引起咳嗽、肺炎、肺水肿等。同时还具有麻醉作用。
⑶. 可与水、麻w痘w传w媒w在线入口-在线免费完整版~高清片、酸、碱、醇反应。
Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)